Surface properties of silicone rubber for sensor applications

Dariusz Szmigiel 1Krzysztof Domański 1Piotr Prokaryn 1Cyrille Hibert 2Arnaud Bertsch 3Elzbieta Pamula 4Anna Ścisłowska-Czarnecka 5Janusz W. Sobczak 6Piotr Grabiec 1

1. Institute of Electron Technology (ITE), al. Lotników 32/46, Warszawa 02-668, Poland
2. Ecole Polytechnique Fédérale de Lausanne. Microsystems Laboratory STI-LMIS (EPFL), Lausanne CH-1015, Switzerland
3. Ecole Polytechnique Fédérale de Lausanne, Centre of MicroNanoTechnology CMI (EPFL), Lausanne CH-1015, Switzerland
4. AGH University of Science and Technology (AGH), al. Mickiewicza 30, Kraków 30-059, Poland
5. Academy of Physical Education, Faculty of Anatomy (AWF), Al. Jana Pawła II 78, Kraków 31-571, Poland
6. Polish Academy of Sciences, Institute of Physical Chemistry, Kasprzaka 52/56, Warszawa 01-224, Poland


The versatility of silicone polymers, their physical and chemical attributes enable them to be used in a wide band of applications as e.g.: an interconnection between two silicon wafers, a spring material in accelerometers or as the ion selective membranes for ISFETs. Polysiloxanes can also be used in mechanical and chemical decoupling of biomedical micro devices from their environment. Since silicone precursors are viscous it is possible to form substrate or coating films by spin coating method. Polysiloxanes are not photo-definable and cannot be photolithographically treated. Among the possible ways to pattern silicon elastomers is plasma processing. Silicones can be effectively etched and/or permanently modified using fluorine-containing plasma. This treatment, however, may also cause unwanted modification in morphology and surface contamination with fluorine compounds such as CxFy or with a mask material e.g. aluminum. Uncontrolled surface changes may turn an initially non-cytotoxic material into a cytotoxic one. The chemical composition, roughness and wettability are believed to directly influence the cell viability and adhesion. That is why the surface purity and proper morphology after processing are key factors for biomedical applications. In this work we studied the fluorine-based plasma treatments of a highly popular silicone elastomer based on poly(methylhydrogensiloxane-co-dimethylsiloxane) and their potential effects on BioMEMS devices. Plasma experiments were performed in both RIE and ICP reactors using CF4, SF6 and O2 gases. The surface morphology and wettability were investigated by means of SEM and contact angle measurements, respectively. The chemical composition of post-etch remnants was analysed by XPS. In order to estimate the cytocompatibility of plasma treated elastomer the standard MTT and CV tests were used. The surface morphology was found to be very dependent on the discharge condition (RIE/ICP) and temperature treatment. The polysiloxane surface appeared to preserve or even improve its hydrophobic properties after fluorine containing plasma exposure. The contact angle values varied between 110° and 140°, depending on the treatment temperature and plasma chemistry. The most hydrophobic surface consisted of tiny, irregular pillars covered with conformal fluorocarbon film. The XPS analysis showed that the polysiloxane surface enriched with fluorine. The amount of fluorine found on the surface was three times higher after the treatment in CF4 plasma than in SF6 one. Despite some contamination and morphology changes the results of the preliminary cytotoxicity study appeared to be very promising: cell viability on a raw and all plasma treated polysiloxane was very high and comparable to control. Such a result is important if the plasma treated polysiloxanes are considered for use in BioMEMS application.
This work has been partly supported by the European Commission - the Healthy Aims Project IST-2002-1-001837.


Legal notice
  • Legal notice:

    Copyright (c) Pielaszek Research, all rights reserved.
    The above materials, including auxiliary resources, are subject to Publisher's copyright and the Author(s) intellectual rights. Without limiting Author(s) rights under respective Copyright Transfer Agreement, no part of the above documents may be reproduced without the express written permission of Pielaszek Research, the Publisher. Express permission from the Author(s) is required to use the above materials for academic purposes, such as lectures or scientific presentations.
    In every case, proper references including Author(s) name(s) and URL of this webpage: must be provided.


Related papers
  1. Impact of the structural funds (POIG) initiative on microsystem technology development in Poland (MINTE and MNS-DIAG projects)
  2. Electronic and optical properties – As and As+Sb doped ZnO grown by PA-MBE
  3. Bioactive glass-modified composites for bone tissue engineering
  4. Molecularly imprinted polymer based electrochemical sensors for flow injection determination of adrenaline
  5. Comparative study of hydroxyapatite and hydroxyapatite mixed with bioglass coatings for metallic implants, deposited by PLD method.
  6. Structure and properties of the multilayers produced on Inconel 600 by PACVD method with the participation of trimethylaluminum vapours
  7. Nanoparticles of Palladium in Polyacetylene or Polyaniline Matrix and Their Activity in Model Hydrogenation Reaction
  8. Pt L2 and L3 Absorption Studies of Pt-doped Polymers
  9. Gold supported on ceria and ceria-alumina promoted by molibdena for complete hydrocarbons oxidation
  10. Composition, structure, surface topography, and electrochemical properties of electrophoretically deposited fullerene films
  11. Microsystem Technology as a Road from Macro to Nano-world. New Opportunities Created by National Centre of Silicon Micro- and Nanotechnology.
  12. Elaboration and characterization of biodegradable scaffolds from poly(L-lactide-co-glycolide) copolymer synthesized with low-toxic zirconium acetylacetonate.

Presentation: Poster at SMCBS'2007 International Workshop, by Dariusz Szmigiel
See On-line Journal of SMCBS'2007 International Workshop

Submitted: 2007-09-07 10:25
Revised:   2009-06-07 00:44