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Peculiarities of CaO·6Al2O3 formation using low temperature combustion synthesis |
Robert Ianoş 1, Ioan Lazău 1, Cornelia Păcurariu 1, Paul C. Barvinschi 2 |
1. Politehnica University of Timişoara, P-ţa Victoriei no. 2, Timisoara 300006, Romania |
Abstract |
The paper presents for the first time a new version of the solution combustion synthesis with applications in the CaO·6Al2O3 direct formation, without any additional thermal treatments. The starting point was the premise - confirmed in our previous results - that there is a predilection of metal nitrates with respect to certain fuels. The used raw materials were: Ca(NO3)2·4H2O, Al(NO3)3·9H2O, urea, glycine and β-alanine. The experimental determinations evidenced that glycine or β-alanine lead to the formation of an amorphous reaction product, whereas urea leads to the formation of a phase mixture consisting of CaO·6Al2O3 and α-Al2O3. On the other hand, the use of a stoechiometric fuel mixture containing urea and β-alanine alongside the desired metal nitrates ensures the straight formation of a pure, well-crystallized CaO·6Al2O3, without any subsequent calcination step. The experimental results prove that the version we suggested - the use of a fuel mixture - is definitely better than the traditional version of the combustion synthesis, based on using a single fuel. |
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Presentation: Poster at E-MRS Fall Meeting 2007, Symposium A, by Robert IanoşSee On-line Journal of E-MRS Fall Meeting 2007 Submitted: 2007-02-20 09:42 Revised: 2009-06-07 00:44 |