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Growth and characterization of (Co,Fe)Si2 solid solution crystals

Wojciech Gurdziel ,  Jacek Krawczyk ,  Zygmunt Wokulski 

University of Silesia, Institute of Materials Science, 12, Bankowa Str., Katowice 40-007, Poland

Abstract

Metal disilicides are good thermal and electrical conductors, possess a high hardness and chemical stability. They have properties which are the most required in microelectronic fields. There are used in VLSI and ULSI circuits.
One of disilicides, which possesses above mentioned specificity is CoSi2. It crystallizes in C1 (fluorite) type of crystal structure (space group). From the electrical properties CoSi2 can be classified into metallic silicides. It can be doped with different elements for far possibility of changing their properties. In our work we chose iron as a dopant thanks to semiconducting character of β-FeSi2 so the mean goal of this work was obtaining of (Co, Fe)Si2 solid solution crystals.
Four melting processes were performed. Each of melts included different percent of iron contents, from 1 at.% to 50 at.% of Fe. Melting process was conducted by Bridgman method in the furnace with vertical temperature gradient under inert atmosphere. Raw materials: Co (99,8%), Fe (99,98%) and Si (99,999%) (weighed from 15g to 20g) were placed in alumina crucibles and melted at a temperature 1550ºC. Next crucibles with melt were slowly pulled out from the high temperature zone.
Obtained samples of Co1-xFexSi2 have been subjected to metallography observation, X-ray and mechanical properties research. Metallography observation shown three different separate phases which were confirmed by X-ray phase analysis. Laue patterns shown that Co1-xFexSi2 for x > 1.0 at.% of Fe ingots were not monocrystalline. It was also shown that the growth of Co1-xFexSi2 solid solution crystals is possible only for x = 1 at.% of Fe.

 

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Related papers

Presentation: Poster at Joint Fith International Conference on Solid State Crystals & Eighth Polish Conference on Crystal Growth, by Jacek Krawczyk
See On-line Journal of Joint Fith International Conference on Solid State Crystals & Eighth Polish Conference on Crystal Growth

Submitted: 2007-01-15 12:01
Revised:   2009-06-07 00:44