From the data obtained in TA and electrochemical studies, the phase diagram for the system thallium(I) telluride - indium(III) telluride was constructed. It follows from the diagram that in the system:

- a compound is formed of component molar ratio Tl₂Te : In₂Te₃ = 5:6 to which a formula Tl₁₀In₁₂Te₂₃ may be ascribed.

- another compound is formed of component molar ratio Tl₂Te : In₂Te₃ = 4:3 to which a formula Tl₈In₆Te₁₃ may be ascribed;

- the compound Tl₈In₆Te₁₃ forms terminal solid solution (γ) on the Tl₁₀In₁₂Te₂₃ matrix 5.5 mol. % wide i. e. from 49.0 mol. % In₂Te₃ to 54.5 mol. % In₂Te₃;

thallium(I) telluride forms terminal solid solution (α) in a peritectic reaction at 723.2 K with the compound Tl₈In₆Te₁₃ within the range 0 - 30 mol. % In₂Te₃;

- the compound Tl₁₀In₁₂Te₂₃ and In₂Te₃ form eutectic of composition 84.5 mol. % In₂Te₃ and melting point 922.8 K, and a terminal solid solution (β) 5 mol. % wide.

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