Boron and Boron-Nitrogen Analoga of Organic Reactive Intermediates

Holger F. Bettinger 

Ruhr Universität Bochum Organische Chemie II, Universitätsstr. 150, Bochum 44780, Germany

Abstract

The boron analogues of carbenes, borenes or borylenes, are highly reactive and have hardly been characterized by direct spectroscopic techniques. We here report on the first generation and spectroscopic characterization of phenylborylene (1) from Bisazidophenylborane (2) und on some of its photochemically initiated reactions in inert gas matrixes.

rxn2.bmp

Furthermore, we describe the first spectroscopic characterization of a borylnitrene (3), a BN analogue of vinylidene R2CC, and its thermal and photochemical reactivity in matrixes.

rxn2.bmp

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Presentation: oral at 18th Conference on Physical Organic Chemistry, Symposium 2, by Holger F. Bettinger
See On-line Journal of 18th Conference on Physical Organic Chemistry

Submitted: 2006-05-31 15:31
Revised:   2009-06-07 00:44
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