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Oxide and nitride nanocomposite coatings deposited by Pulse Magnetron Sputtering

Heidrun Klostermann 1Fred Fietzke Thomas Modes Olaf Zywitzki 

1. Fraunhofer Institute for electron beam and plasma technology (FEP), Winterbergstraße 28, Dresden 01326, Germany

Abstract

Pulse Magnetron Sputtering proves its versatility and capability in the production of high quality coatings on 3D-parts of various functions. It is a high-rate deposition technique for films of excellent properties, especially from dielectric materials. Examples of actual state-of-the-art functional coatings deposited by pulse magnetron sputtering will be presented, which are nanocomposite oxide and nitride coatings.

For the deposition of nanocomposite coatings, reactive co-sputtering of different target materials allows a fine adjustment of the film composition to generate the specific two-phase structures that exhibit outstanding mechanical properties. In this way, nc-ZrN/Al, and nc-Al2O3/ZrO2 have systematically been generated with generally good adhesion and maximum hardness in the order of 30 GPa in both systems. In the nitride system Zr-Al-N, structure-related hardness increase is achieved for a small fraction of aluminium in the coating. In the oxide system Al-Zr-O, depending on the composition, crystalline phases of g-alumina or tetragonal zirconia can be stabilised.

Another oxidic nanocomposite system attracting much interest is the system nc-TiO2/Ti, where crystallites of TiO2 are embedded in a Ti-matrix. Pulse Magnetron Sputtering allows the tailored generation of anatase or rutile phase through the choice of pulse parameters and deposition conditions. Properties like hydrophilicity and photocatalytic activity are investigated as a function of crystalline phase formation and stoichiometry in the nc-TiO2/Ti system.

 

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Presentation: Oral at E-MRS Fall Meeting 2006, Symposium A, by Heidrun Klostermann
See On-line Journal of E-MRS Fall Meeting 2006

Submitted: 2006-05-22 08:30
Revised:   2009-06-07 00:44