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Nonexponential photoionization of the DX related centers in indium doped Cd1-xMnxTe. On the relationship between the stretched exponential and two-exponential relaxation models. |
Justyna Trzmiel 1, Karina Weron 1, Ewa Popko 1, Piotr Becla 2 |
1. Wroclaw University of Technology, Institute of Physics, Wybrzeże Wyspiańskiego 27, Wrocław 50-370, Poland |
Abstract |
The kinetics of phototransients due to the presence of defects in semiconductors is commonly analyzed in the terms of the multiexponential fitting or by means of the stretched exponential function.The motivation of this paper is to explain the relationship between both models.For this purpose the kinetics of phototransients due to DX centers in indium doped Cd0.93Mn0.07Te crystals grown by the Bridgman method were studied.Photoconductivity transients, measured at 77K for different photon fluxes with fixed photon energy,were analyzed. The obtained data can be well fitted with the stretched exponential function.On the other hand, it appears that the transients are also well fitted by a superposition of two weighted exponents with the short and long time constants b1and b2, respectively.To explain the result we propose the probabilistic representation of the relaxation function Φ(t)=<e-βt>, given by a weighted average of the exponential decay with respect to the distribution of the random relaxation rate β,representing the intrinsic nonexponential behavior of the entire system.As it is well-known from probability theory, such an average can be expressed either as a sum of weighted exponentials Σpie-bit,if β takes positive discrete values bi with probabilities pi,or as the integral ∫e-btρ(b)db,if β takes values from [0,∞) with probability ρ(b)db.This "dual" representation of the relaxation function explains a relationship between the stretched exponential pattern and the two-exponential fitting.In the studied case the probabilities p1,p2 of taking two different time constans b1,b2 attributed to the two-step photoionization of the DX centers, are shown to be in agreement with the long-tailed stable distribution of the effective relaxation rate corresponding to the stretched exponential relaxation response. |
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Presentation: Oral at E-MRS Fall Meeting 2006, Symposium F, by Justyna TrzmielSee On-line Journal of E-MRS Fall Meeting 2006 Submitted: 2006-05-13 18:14 Revised: 2009-06-07 00:44 |