Search for content and authors
 

Formation of bimetallic oxide nanoparticles from alkoxide precursors.

Lucjan Jerzykiewicz ,  Józef Utko ,  Eugeniusz Zych ,  Piotr Sobota 

University of Wrocław, Faculty of Chemistry, Joliot-Curie 14, Wrocław 50-383, Poland

Abstract

Multimetallic oxides, because of their specific properties may represent an important class of new materials. Unfortunately the high processing temperatures typically applied make them less useful for nanoscaled materials. Because of this to generated bimetalic oxide we use molecular single-source alkoxdie precursors which are suitable for formation of oxides or other materials.

During our investigation of manganese systems, we have found that heterometallic alkoxide precursors are excellent to generate oxide materials. The method allows these oxides to be formed in one step at molecular level. In this communicaion synthesis and crystal structure of alkoxide precursors - [Mn2Ba2(OC6H4OCH2CH3)8(CH3OCH2CH2OH)2] (1) will be presented. The thermogravimetric analysis (TGA) investigation with the temperature varied from 25 to 1000°C in steps of 10°C shows that decomposition of 1 is noticeable at about 400 oC in dinitrogen. The properties of the resulting oxide: BaMnO3 were characterized by powder X‑ray diffraction spectroscopy and scanning electron microscopy.

ACKNOWLEDGMENT We thank the State Committee for Scientific Research (Poland) for support of this research (Grant 3 T09A 083 26).

 

Legal notice
  • Legal notice:
 

Related papers

Presentation: Poster at E-MRS Fall Meeting 2006, Symposium D, by Lucjan Jerzykiewicz
See On-line Journal of E-MRS Fall Meeting 2006

Submitted: 2006-05-11 12:26
Revised:   2009-06-07 00:44