Composites with layered structures - laminates, because of specific properties, have an important, permanent place in a materials science research. Recently, an interesting group of laminates have been discussed and developed. They are called nanolaminates because of layered structure in a nanoscale. The paper summarises author's works on preparation and testing of a new group of nanolaminates - ceramics based on Ti[3]SiC[2]. A possibility of preparation of sinterable Ti[3]SiC[2 ]powders by Self-Propagating High-temperature Synthesis (SHS) from powdered substrates is shown. The powders can be densified into Ti[3]SiC[2 ]-based polycrystals using pressureless sintering or hot-pressing. The final materials have a very specific laminar character in nano and micro scale. Such structure can be correlated with a relatively low hardness, high elastic modules, high fracture toughness, and high corrosion and thermal shock resistance. The examples of preparation of ceramic composite nanolaminates built from carbides, nitrides and intermetalics, as well as a general perspectives of nonolaminate materials are discussed.
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