Search for content and authors |
Structure and properties of superhard cBN composites with a nanostructured binding |
Tetiana A. Garbuz |
V. Bakul Institute for Superhard Materials NAS of Ukraine, 2, Autozavodska str., Kiev 04074, Ukraine |
Abstract |
The process for obtaining PCBN composites by the reaction sintering powders cBN with Al at pressures of 7.7 and 4.2 GPa with a preliminary dispersion of Al in the mixture at p = 2.5 GPa and T = 1300 K is designed in the ISM NASU. The problems of sintering nanopowders cBN are following: high cohesive activity, tendency to a phase transition cBN→hBN; difficulty infiltration due to the small size of the pores. cBN submicron powder advisable used in the mixture cBN-Al, in submicron cBNthe 15 % nanofraction located on the surface of larger particles. Nanosized particles before others interacted with Al. The reaction product AlN inherit the size and morphology of nanoparticles cBN. Instead of a continuous frame cBN, resulting in sintering micron, highly dispersed structure of phase cBN in the shell with AlN nanoscale grains (15-30 nm) is formed. The material has a high fracture toughness - 10.5 MPa∙m1/2 at a hardness 27 GPa. Nanocomposites system cBN-Al-TiB2 were obtained by the same principle, where a high modulus TiB2 in the mixture acts as an activating, alloying and modifying additives. Here nanophases were the reaction products - solid solutions Ti x Al 1-x B 2 (5-200 nm), Al x B y N z (≤ 100 nm) and on the boundary between cBN and Ti x Al 1-x B 2 formed Ti68B10N22 (≤ 30 nm). Structure of composite with strain hardening frame cBN and high modulus nanostructured binding formed in the nanocomposite cBN-Al-TiB2. The new composite has Knoop hardness 34-35 GPa and fracture toughness 6.5 MPa∙m1/2. |
Legal notice |
|
Presentation: Poster at Nano and Advanced Materials Workshop and Fair, by Tetiana A. GarbuzSee On-line Journal of Nano and Advanced Materials Workshop and Fair Submitted: 2013-06-05 15:47 Revised: 2013-06-05 15:47 |