ELECTRONICALLY TUNABLE PROPERTIES OF NANOCRYSTALLINE METALS Harald Drings1, Raghavan Nadar Viswanath1, Roland Würschum2, Jörg Weissmüller1 and Herbert Gleiter1 - 1 Forschungszentrum Karlsruhe, Institute for Nanotechnology Postfach 3640 76021 Karlsruhe,Germany,Tel +49-7247-82-6378, Fax +49-7247-82-6368 - 2 Technical University of Graz, Institute for Technical Physics, Petersgasse 16, A-8010 Graz, Austria
The surface charge density of materials can be influenced by an externally applied field [1]. Due to the large fraction of surface atoms in nanocrystalline (n-) materials, a field-induced variation in the surface charge density should lead to a reversible change of structural and physical properties. To verify this assumption, in-situ measurements of the lattice parameter d of n-Pt and the magnetic susceptibility of n-Pd, in dependence of charging, were performed. Electrochemical double layer formation in an electrochemical cell was used for charging. Reversible changes of the lattice parameter and the magnetic susceptibility were observed.
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