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Noncentrosymmetric halide borate: K3B6O10Cl

Shilie Pan 

Xinjiang Technical Institute of Physics and Chemistry Chinese Academy of Sciences(Urumuqi)830011 P.R.China, Beijing south road 40# add 1#, urumuqi 830011, China

Abstract
A perovskite-like phase, K3B6O10Cl exhibits a large second harmonic response about four times that of KH2PO4 (KDP) and is transparent from the deep UV (180 nm) to middle-IR region. A high quality single crystal of K3B6O10Cl with dimensions up to 30 × 15 × 7 mm3 was successfully grown by the top-seeded solution growth method. Crystal morphologies and growth habits of K3B6O10Cl grown with seeds oriented along [101] and [211] were studied, and the best growth direction was obtained., The refractive indices of the crystal were measured by the minimum deviation technique and fitted to the Sellmeier equations[1].The nonlinear optical coefficients have been determined by the method of Maker fringes at λ=1064 nm. The suitable nonlinear optical coefficients as well as comparatively easy crystal growth make the K3B6O10Cl crystal a promising candidate for NLO materials[2-9].

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Presentation: Oral at 17th International Conference on Crystal Growth and Epitaxy - ICCGE-17, Topical Session 6, by Shilie Pan
See On-line Journal of 17th International Conference on Crystal Growth and Epitaxy - ICCGE-17

Submitted: 2013-03-28 06:38
Revised:   2013-07-18 20:29