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Correlation between applied pressure, properties and microstructure in pure ultrafine WC powder consolidated by Spark Plasma Sintering (SPS)

Salvatore Grasso 1,2Yoshio Sakka 3Giovanni Maizza 4

1. World Premier International Reserch Center Initiative on Materials Nanoarchitronics MANA (NIMS), 1-2-1 Sengen, Tukuba 305-0047, Japan
2. Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-2-1 Sengen, Tsukuba 305-0047, Japan
3. National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba 305-0047, Japan
4. Politecnico di Torino - Dipartimento di Scienze dei Materiali e Ingegneria Chimica, C.so Duca degli Abruzzi 24, Torino 10129, Italy

Abstract

A combined experimental/numerical methodology is developed to fully consolidate pure ultrafine WC powder by means of Spark Plasma Sintering (SPS) operating under a current-control mode. The investigated applied pressure range from 5 to 80 MPa while the current intensity is held constant to 1400 A.

The developed SPS model employs a moving-mesh technique to account for the electro-thermal contact resistance change during shrinkage and punch sliding. The pressure dependence on the electro-thermal contact resistance is also taken into account by the model.

The experimental and numerical results clearly show the effects of pressure on the microstructure and hardness along the sample radius.

By increasing sintering pressure, complete densification was obtained reducing the peak temperature measured at die surface. By combining experimental and modeling results, a direct correlation among compact microstructure, homogeneity and sintering parameters, such as temperature and applied pressure, can be established.

 

 

 

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Presentation: Oral at E-MRS Fall Meeting 2008, Symposium I, by Salvatore Grasso
See On-line Journal of E-MRS Fall Meeting 2008

Submitted: 2008-06-03 10:43
Revised:   2009-06-07 00:48