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The correlation between the crystal structure and magnetic ordering in ternary RT2X2 and RTX3 compounds

Wieslawa Bażela 

Cracow University of Technology, Institute of Physics (PK), Podchorążych 1, Kraków 30-084, Poland

Abstract

In this paper the influence of the crystal structure on the magnetic ordering in ternary RT2X2 and RTX3 (R is the rare earth metal, T the 3d, 4d or 5d transition metal and X = Si or Ge) compounds is studied. These compounds crystallize in three types of crystal structure which have been derived from the tetragonal BaAl4 structure: in a body-centered ThCr2Si2 type structure (space group I4/mmm), in a primitive CaBe2Ge2-type (space group P4/nmm) and in a body-centered structure BaNiSn3 (space group I4mm). The position of R atoms in these crystal structures causes the anisotropic character of magnetic interaction between the R ions, and the Ising-like model can be used to explain the stability of magnetic ordering. In the rare-earth sublattice the different magnetic structures, namely, collinear AFM and non-collinear AFM cosinusoidally modulated, are observed. The analysis of the magnetic structure of RT2X2 (X = Si, Ge) compounds reveals a strong dependence of magnetic ordering on the a/c ratio (a, c are the lattice constants). For a/c < 0.415, a simple collinear ordering is observed (for example, in (Nd,Tb,Dy,Ho,Er)Rh2X2, PrCu2X2, RIr2Si2, RCo2X2 – AF I type; in NdFe2Si2 and (Nd, Pr)Fe2Ge2 – AF II type and in (Gd, Tb, Dy, Ho, Er)Cu2X2 – AF IV type), while the compounds with a/c > 0.415 exhibit oscillatory magnetic structure (for example, in (Tb, Dy, Ho, Er)Os2Si2; in RPd2X2 and (Tb, Dy, Er)Pd2Si2 – LSW IV; in RRu2X2 and TbRu2X2 – LSW II. These relations are performed for large numbers of RT2X2 compounds. Another types of magnetic structure than result from this relation are observed for compounds with T = Mn, Fe and Au (for example, in TbFe2X2 – LSWIV).

The various magnetic structures observed above can be interpreted by the RKKY model of interactions. Such conclusion is supported by the fact that the nearest R – R distance is equal to the lattice parameters a of ~ 0.4 nm (in plane) and ~ 0.6 nm (between plane) and that these compounds are good electrical conductors. In isotropic RKKY model, the Fermi vector is dependent strongly on both the a/c ratio and on the number of free electrons Z per magnetic ion. The analysis of modulated magnetic structures RRu2Si2 (R = Tb – Er) based on RKKY model indicates that the order is stable for Z ≈ 3. This is in agreement with discussed covalent bonds in tetrahedron TX4 in ThCr2Si2-type crystal structure.

The Néel temperatures in the RPd2Si2, RRu2Si2 and RRh2Si2 series depend randomly on the number of f-electrons. This fact suggests that the influence of crystalline electric field (CEF) should be also considered in explaining the magnetism in these compounds. The CEF at the R site can strongly affect the magnetic properties of the RT2X2 systems. The orientation of magnetic moment with respect to the fourfold axis is connected with the sign of the (CEF parameter). The positive sign at coefficient indicates that the magnetic moment is normal to the tetragonal axis or creates an angle φ with it. Its negative value indicates that the moment is aligned along the c-axis. As an example, the magnetic ordering in TbIrSi3 and TbIr2Si2 will be discussed.

 

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Presentation: Poster at Joint Fith International Conference on Solid State Crystals & Eighth Polish Conference on Crystal Growth, by Wieslawa Bażela
See On-line Journal of Joint Fith International Conference on Solid State Crystals & Eighth Polish Conference on Crystal Growth

Submitted: 2007-01-25 10:58
Revised:   2009-06-07 00:44