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Effects of ceiling temperature on In incorporation and optical properties of InGaN epilayers grown by two-heater MOCVD reactor

Shao-fu Fu 1Wei-Kuo Chen 1Fang-Wei Li 1Bo-Wei Liao 1Wen-Cheng Ke 2Szu-Yu Chen 1

1. National Chiao-Tung University, Institute and Department of Electrophysics, 1001 Ta Hsueh Road, Hsinchu 30050, Taiwan
2. Yuan Ze university,Department of mechanical engineering, Taoyuan 32003, Taiwan

Abstract

  We have conducted a series of InGaN growths using a modified MOCVD horizontal reactor, namely two-heater MOCVD reactor, by varying substrate temperature, ceiling temperature and growth pressure. When the ceiling temperature is fixed at 800oC, the measured InN growth efficiency in InGaN exhibits an activation energy of 0.97 eV for substrate temperature >650oC, a value close to InN decomposition energy (1.2 eV), indicating the InGaN growth at high temperatures here is governed mainly by the dissociation of InN, similar to the case by conventional MOCVD. More interesting results are observed on the series of ceiling temperture samples. At a substrate temperature of 625oC, where the decomposition of InN, if exists, is insignificant, the InN growth efficiency is observed to remain almost constant with increasing ceiling temperature and begin to drop considerably for ceiling temperature >800oC. Such a declining in InN growth efficiency is ascribed to the parasitic reactions involved with TMIn reactants in the gas phase, as confirmed by the results of growth pressure experiment.

  Additionally, we have found that the PL properties of InGaN films strongly depend on the ceiling temperature. As the ceiling temperature is increasing from 700 to 800oC, the peak energy of films grown at 625oC is found to be nearly unchanged at ~1.73 eV (730 nm), however, its intensity improves remarkably, nearly by two orders of magnitude. Our results demonstrate that the use of ceiling temperature can effectively improve the luminescence efficiency of MOCVD-grown InGaN film, which may shed a light on the exploration of high quality InGaN materials emitting at long wavelengths.

 

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Presentation: Oral at 17th International Conference on Crystal Growth and Epitaxy - ICCGE-17, General Session 10, by Shao-fu Fu
See On-line Journal of 17th International Conference on Crystal Growth and Epitaxy - ICCGE-17

Submitted: 2013-04-15 15:43
Revised:   2013-04-16 05:38