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Growth and characterization of birefringent crystal NaNO3

Wei Xiong 1Liang Chen 1Lingxiong Huang 2Yao Zhou 1Baoliang Lu 3Hui Yuan 1

1. Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai 200050, China
2. Fujian Institue of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
3. Shanghai Jingcui Material Technology Co., Ltd., Shanghai 200062, China

Abstract

With a bigger birefringence than calcite, sodium nitrate (NaNO3) single crystals might have potential applications in opto-isolators, circulators and polarizing prisms. However, it is difficult to grow large-size NaNO3 crystals for their thermal conductivity anisotropy and phase transition at 275 oC. In this paper, crack-free NaNO3 crystals with size of Φ20×100mm3 were prepared by Bridgman method with lower growth rate and lower interface temperature gradient. The behaviors of time dependent on transmittance were measured and analyzed. The refractive indices of NaNO3 crystal at wavelengths of 0.4730, 0.5320, 0.6328, 1.064 and 1.338 μm were measured by selfcollimating method. From which, we fitted and obtained the Sellmeier’s equation of NaNO3 crystal. Moreover, the photoluminescence spectra were detected under the excitation of 240 nm, and NaNO3 crystal presented its fluorescence around 425 nm.         

 

Auxiliary resources (full texts, presentations, posters, etc.)
  1. POSTER: Growth and characterization of birefringent crystal NaNO_{3}, JPEG image data, EXIF standard 2.3, 1.9MB
 

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Presentation: Poster at 17th International Conference on Crystal Growth and Epitaxy - ICCGE-17, General Session 2, by Wei Xiong
See On-line Journal of 17th International Conference on Crystal Growth and Epitaxy - ICCGE-17

Submitted: 2013-04-15 12:54
Revised:   2013-07-26 14:34