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Improvement of multi-crystalline silicon solar ingot growth by using diffusion barriers

Chung-Wen Lan ,  Yu-Ting Weng ,  Chih-Chen Hsieh 

Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei city 10617, Taiwan

Abstract

The control of impurity and nucleation is crucial to the ingot quality and yield in the directional solidification of multi-crystalline silicon for solar cells. The major impurities, such as metals, are mainly from the quartz crucible and the silicon nitride coating. The use of high-purity materials mitigates of the problem, but this increases the cost. Another way is to use diffusion barriers between silicon and these materials to reduce the incorporation of impurities. We have explored several materials and layer configurations for the diffusion barriers, and the results are promising. Both the ingot lifetime and yield have been improved. The wetting and nucleation behaviors of the diffusion barriers in contact with molten silicon are also reported and discussed.

 

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Related papers

Presentation: Oral at 17th International Conference on Crystal Growth and Epitaxy - ICCGE-17, Topical Session 5, by Chih-Chen Hsieh
See On-line Journal of 17th International Conference on Crystal Growth and Epitaxy - ICCGE-17

Submitted: 2013-03-28 17:51
Revised:   2013-06-02 13:44