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Bioinspired design of SrAl2O4:Eu2+ phosphor

Mariya H. Kostova 1Cordt Zollfrank 1Miroslaw Batentschuk 2Albrecht Winnacker 2Peter Greil 1

1. University of Erlangen-Nürnberg, Glass and Ceramics, Martenstr.5, Erlangen 91058, Germany
2. University of Erlangen-Nürnberg, Elctrical Engineering Materials, Erlangen 91054, Germany

Abstract

A cellular phosphor material based on Sr0.97Al2O4:Eu0.03 was manufactured via vacuum assisted infiltration of wood tissue (Pinus sylvestris) with a precursor nitrate solution. The major crystalline phase was monoclinic SrAl2O4, detected by X-ray diffraction (XRD). Due to the uniform arrangement of rectangular shaped tracheidal cells of the pine wood specimens, the nitrate solution penetrated homogeneously into the porous structure. The microstructure of the biotemplated Sr0.97Al2O4:Eu0.03 phosphor was examined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Energy-dispersive X-ray analysis (EDX) proved the homogeneous conversion of the wood cell wall into Sr0.97Al2O4:Eu0.03 struts. The optical properties of the resulting phosphor material were determined by photoluminescence spectroscopy (PL) at room temperature and cathodoluminescence spectroscopy (CL) in the SEM. The biotemplated Sr0.97Al2O4:Eu0.03 showed a characteristic green emission at 530 nm (2.34 eV). Shaping biomorphous SrAl2O4:Eu2+ phosphor with a microstructure pseudomorphous to the bioorganic template anatomy offers novel approach for designing highly oriented phosphor materials to be used in two dimensional detector arrays.

 

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Related papers

Presentation: Oral at E-MRS Fall Meeting 2008, Symposium H, by Mariya H. Kostova
See On-line Journal of E-MRS Fall Meeting 2008

Submitted: 2008-05-05 13:20
Revised:   2009-06-07 00:48