Scanning electrochemical microscopy - a tutorial lecture

Wolfgang Schuhmann 

Ruhr-Universität Bochum, Anal. Chem. - Elektroanalytik & Sensorik (ELAN), Universitätsstr. 150, Bochum 44780, Germany

Abstract

The tutorial lecture will provide an overview of scanning electrochemical microscopy (SECM) and its prerequisites, limitations and fields of applications.

The main aspects will be:

  • Scanning probe microscopy as a tool for gathering localized physical, topographic and electrochemical information.
  • System set-up, imaging modes, achievable resolution. Combination with electrochemistry.
  • Fabrication of micro- and nanoelectrodes and specific characteristics
  • Feedback mode, generator collector mode, impedance and redox competition mode of SECM
  • Application of SECM in biosensor development, material research, micro- and nanostructuring of surfaces, catalyst evaluation

Related papers
  1. Visualisation of local catalyst activity towards oxygen reduction in hydrochloric acid solution with RC-SECM
  2. Determination of optimum imaging contrast in AC - SECM
  3. Electrochemical impedance spectroscopy (EIS) for detection of DNA hybridization in presence of intercalators
  4. Shearforce-based distance control in scanning electrochemical microscopy
  5. Metalloporphyrin modified glassy carbon electrodes for oxygen reduction: Investigation of local electrocatalytic activity
  6. Mathematical tools for characterization of spatial variability of surface activity based on SECM images
  7. Visualisation of the effect on catalytic activity of increasing Pt agglomerate sizes using constant-distance mode SECM in a competition mode
  8. Reagentless biosensors based on mediator-modified electrodeposition hydrogels
  9. Microelectrochemistry. From Materials to Biological Applications

Presentation: Tutorial lecture at SMCBS'2007 International Workshop, by Wolfgang Schuhmann
See On-line Journal of SMCBS'2007 International Workshop

Submitted: 2007-09-01 12:18
Revised:   2007-10-24 19:34
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